Nucleation products of ligated nanoclusters unaffected by temperature and reducing agent.

نویسندگان

  • John M Pettibone
  • Nicole R Reardon
چکیده

Atomically uniform nucleation products of ligated metal nanoclusters are observed irrespective of reduction conditions for metal-bidentate ligand systems. Monodentate ligands are not reported to wield similar control, indicating steric contributions of complexing ligands may be as important as their electronic structure for synthesizing small nanoclusters.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Reaction network governing diphosphine-protected gold nanocluster formation from nascent cationic platforms.

We identify the reaction network governing gold monolayer protected cluster (MPC) formation during the reduction of Au(PPh(3))Cl and L(5) (L(5) = 1,5-bis(diphenylphosphino)pentane) in solutions. UV-vis spectroscopy and electrospray ionization mass spectrometry (ESI-MS) monitored the formation of ligated Au(x): 6 ≤ x ≤ 12 clusters, which comprise the reaction intermediates and final products. In...

متن کامل

Temperature-Dependent Size-Controlled Nucleation and Growth of Gold Nanoclusters

The electrochemical method of synthesis of gold nanorods in micelles gives substrate solutions that upon spotting and heating on a transmission electron microscope (TEM) substrate result in the nucleation and growth of small gold nanoclusters of narrow size distribution. The size of the nanoclusters, and not their numbers, is found to increased with increasing final temperature to which the sub...

متن کامل

Effects of Statically Electric Fields on Freezing Parameters and Microstructures of Button Mushrooms (Agaricus bisporus)

Background and Objectives: Freezing under statically electric fields is one of the novel freezing methods to improve the quality of frozen products by controlling the nucleation process. The objective of this study was to investigate effects of freezing under electrostatic fields on the freezing parameters and microstructures of frozen button mushrooms. Materials and Methods: Mushroom samples w...

متن کامل

Expected nucleation effects of carboxylic acid salts on poly(1-butene)

9,10-Dihydro-9,10-ethano-anthracene-11,12-dicarboxylic acid disodium salt (DHEAS) was synthesized and used as a nucleating agent for poly(1-butene) (iPB). The isothermal crystallization kinetics of iPB having different nucleating agents were investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The results showed that the nucleating agents increased the...

متن کامل

Nucleation and growth of nickel nanoclusters on graphene Moire on Rh(111)

Regularly sized Ni nanoclusters (NCs) have been grown on a graphene Moire on Rh(J 11) . Using scanning tunneling microscopy, we determine that initial growth of Ni at 150 K leads to preferential nucleation of monodispersed NCs at specific sites of the Moire superstructure. However, a defined long-range ordering of NCs with increasing coverage is not observed. Room temperature Ni depos ition lea...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Nanoscale

دوره 4 18  شماره 

صفحات  -

تاریخ انتشار 2012